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The history of the atom

The science of the atom
The word atom comes from the latin word " atomos " meaning indivisible , an atom is the smallest particle of an element that can exist and still contain the properties of that element . There has been found , particles smaller than the atom that make up the atom , these are called sub-atomic particles and consist of protons , neutrons and electrons , even smaller are particles known as quarks , these are too complex to be discussed here and also too , my knowledge of this area of physics is little , there are 6 types of quarks , these shall only be named and not discussed further , they are : up , down , left , right , strange , charm , this is not a joke ppl , I guess the scientist who discovered them was a cool guy . Now we shall discuss how the structure of the atom was formulated , pretty boring if you asked me , but hey , I had to learn it so no harm in telling the story .
The concept of the atom was first conjured in the mind of an old guy called J . J . Thompson in 1902/1907 or so . He thought of the atom as a pudding representing a large ball of postive charge with currants of negative charge arranged randomly but enough to equalize the positve charge , this model was called the , " plum pudding model . " This model I find is stupid but was accepted , later , Ernest Rutherford observed alpha particles passing through a sheet of mica , he thought it solid enough and there were no holes made by this , this made him think . He then instructed his 2 male students , Geiger and Mardsen to investigate this effect , they used a thin sheet of gold foil . Why gold foil you may ask ? Well as I was told by my lessons instructor, it's since gold foil is so malleable that it can be hammered into a very thin sheet without breaking , so thin is this sheet that it's only a few atoms thick , it was not since they were rich and wanted to use gold instead of aluminium foil but because of this reason . They used an apparatus consisting of an evacuated metal sphere , evacuated cause they din't want the air molecules affecting the motion of the alpha particles . They placed a source of alpha particles at a point , then used a thin sheet of gold foil to place in front of the source , they then used a telescope with a zinc sulphide screen which could detect when an alpha particle collided with it as it showed as a flash of light . From this apparatus they observed the deflection of the alpha particles as angles, they found that only 1 in 8000 of these particles was deflected at an angle greater than 90 degrees . This intrigued them , a small few were deflected at 180 degrees , Rutherford once said that it was credible as if you shot a piece of tissue paper and it came back and hit you . An explanation for this is that this proved that the nucleus had a positive charge , the alpha particles are positively charged , being helium nuclei , they would thus be repelled from the nucleus when it came too close to it . There would be an attraction of the alpha particles to the electrons of the atom , but the nucleus , having such a large atomic number would contain a ratio of protons to electron too large to affect the alpha particle . Occasionally the alpha particle came so close to the nucleus that it was repelled from it at a large angle , even more rarely is the head on collision with the nucleus causing a 180 degree deflection .
Another guy called Neils Bohr , connected the quantum theory , Rutherford's model of the atom and some other thing I can't remember now . He said that electrons were situated in shells or orbitals orbiting the nucleus which had a positive charge , the electrons had a negative charge . Later , in 1932 , a fella called J . Chadwick discovered an uncharged particle called the neutron , and suggested it was to have a mass slightly greater than that of the proton , later when it was measured , it was found that this was so , the neutron was slightly heavier than the proton , each is assigned a mass of 1 a.m.u. = 1 u = 1.67 * 10^-27 kg , pretty small if you asked me!
Much of what we think an atom is today was formulated by Neils Bohr , electrons are situated in regions called orbitals , clouds around the nucleus .
Points to note : the diameter of a nucleus - 10^-14m
The diameter of a molecule- 10^-10m
One of my physics teachers once said we'll never be able to see an atom , however there is evidence that when a thin sheet of copper was observed at the highest magnification of an electron microscope, small spheres were seen , equidistant from one another , are these atoms ? I guess they are .



Extinction of the dinosaurs
The extinction of the dinosaurs
Why ?
There are many theories , however I shall only explain one of these , I shall speak from a time 65 million years ago , there was an asteroid heading for the earth , this we know , the actual cause of extinction is theory . This asteroid entered earth's atmosphere , into a land very different from earth today , due to an effect called Continental Adrift , the continents , which are " floating " on a sea of magma below in the mantle , are moving apart . At one point the continents were called pangea , where they were all joined , but that is off the topic , dinosaurs , right , that's the topic . So as I was saying , the asteroid was obviously too large to succumb to the effects of the earth's atmosphere attempting to disintegrate it and it was on a course for the western hemisphere . There is evidence that an asteroid collided with an area on the Yucatan Peninsula , Mexico .
Theories suggest that this collision resulted in an enormous volume of dust being thrown into the atmosphere which was taken by the wind and spread around the earth , being such an enormous volume the cloud of dust blocked off sunlight to plants and resulted in the plants being starved of solar energy necessary for photosynthesis ; plants were unable to provide food for themselves being autotrophic and so died . Herbivores being heterotrophic depended on the plants for food and being the only source of energy in the ecosystem without the plants the herbivores soon died. The carnivores soon followed as they were also heterotrophic and relied on the herbivores for survival , this is one of the theories conjured in the minds of bored scientists .
Another theory , due to the impact of the asteroid , an atomic catastrophe caused all life within a large radius around the site of the collision to die . Animals which survived the catastrophe had to move to other regions of the earth , since the earth was pangea this was no grave problem . The dinosaurs moved to other territory but the atomic collision had effects causing the trek to more fertile land difficult as fertile land was hard to find and they became cannibalistic . The weaker animals were preyed on by the larger and eventually they one by one , unable to survive the tough conditions , died out .
Most scientists do agree that an asteroid collided with the earth in prehistoric times with a fury able to do catastrophic damage , however not all agree that this was the cause of the extinction of the dinosaurs . Recent investigations have shown an element found only on asteroids located on the bones of ancient dinosaurs hinting the cause of their demise , maybe we'll never know .















Tactical feedback-when you press on a button and it springs back at you


Chemical processes

There are three factors which affect the discharge of substances at the electrodes :
The reactivity of the substance
The nature of the electrodes
The concentration of the substance

The reactivity of the substance

The electrochemical series for metals is as follows:
K>Ca>Na>Mg>Al>Zn>Fe>Pb>H>Cu>Ag>Au
The metal lower in this series would be preferentially discharged

The electrochemical series for non-metals is much shorter , it is :
F>SO4.2->NO3.1->Cl>Br>I>OH.1-
As is with metals , it is the substance lower in the series which is preferentially discharged .

The nature of the electrodes

The material of the electrodes affects the discharge of the substances , there are 2 types of electrodes : inert and active . There are only 2 substances used for inert electrodes , they are copper and platinum , these electrodes do not take part in the chemical reaction . Active electrodes do take part in electrolysis , e.g. Copper electrodes , Zinc etc.

The concentration of the substance

The more concentrated the ion in the electrolyte , the greater the chance of it being preferentially discharged .

The extraction of aluminium
This is done from bauxite , bauxite is Al2O3 , the bauxite is first purified , then it is mixed with molten cryolite Na3AlF6 at 900degrees celcius , this is done to lower the melting point of bauxite as an " impurity " added will lower the melting point . Cryolite is chosen as it does not affect the discharge of the elements , aluminium is less reactive than sodium (Na) and so it will be preferentially discharged during electrolysis . A substance known as fluorospar CaF2 can also be added to lower the boiling pt ( Ca is more reactive than Al ) . This mixture is then electolysed, having a lower melting pt reduces the cost of electrolysis . At the anode oxygen is discharged as between oxygen and fluorine (F) , oxygen is the less reactive anion and would thus be preferentially discharged . At the cathode , molten aluminium would be discharged and is tapped off . The apparatus used is a sort of basin in which there are three graphite anodes placed at the top , the entire base of the apparatus is a graphite cathode which is where the molten aluminium collects . The electrolyte , bauxite+cryolite is placed inside the basin .




How Sodium Hydroxide is obtained : the Flowing Mercury Cathode Cell

In this process , concentrated brine is used ( conc.NaCl ) , sodium is obtained by electrolysis since when subjected to the clean surface of a metal(mercury) , the discharge is reversed , hydrogen would normally be discharged but sodium is discharged instead :
Na* + e` -----> Na
Chlorine is in a higher concentration than the OH- ions and so is preferentially discharged as Chlorine gas .
2Cl- -----> Cl2 + 2e`
The sodium then combines with the mercury forming an amalgam
Na + Hg ------> Na/Hg
Water is then run through the apparatus and combines with the amalgam forming sodium hydroxide and hydrogen gas and regenerates pure mercury :
2Na/Hg + 2H2O ------> 2NaOH + H2 + 2Hg
This process is very efficient as expensive mercury is regenerated and both chlorine and hydrogen gas is obtained as a bi product

How Sodium is obtained comercially : the Down's cell

In this cell , the cell is specially constructed to prevent the sodium and chlorine reacting , the process involves the electrolysis of molten sodium chloride mixed with calcium chloride to lower the melting point of sodium using inert electrodes , chlorine gas is obtained at the anode and sodium at the cathode . The anode reaction is :
2Cl- ------> Cl2 + 2e`
The cathode reaction is :
Na` + e`-------> Na
Where molten sodium is obtained .

How ammonia is obtained : the Haber Process

First in this process is obtaining hydrogen , this is obtained by steam reforming , natural gas , methane , is added to steam in the presence of a catalyst under pressure to obtain carbon monoxide and hydrogen gas .
Ni catalyst
CH4 + H2O --------> CO + 3H2
100C , 50atm
Nitrogen is now obtained either by the fractional distillation of liquid air , where the air is compressed to 150-200atm and cooled to -200 degrees celcius till carbon dioxide and water vapour can be removed as solids . The nitrogen and oxygen now remain , with only helium and neon not freezing . Since the boiling point of oxygen is -183 degrees celcius , and that of nitrogen is -196 degrees celcius , the nitrogen is more volatile and through fractional distillation , liquid oxygen is tapped off at the bottom and nitrogen at the top .



Now , ammonia can be obtained as nitrogen and hydrogen gas are combined to give gaseous ammonia
Fe2O3 iron catalyst
N2 + 3H2 ----------> 2NH3
500degrees celcius 200atm.
The unreacted gases are recycled .

The fractional distillation of petroleum

Petroleum is fractionally distilled to give several fractions which are very useful . The petroleum is first treated to remove sulphur which prevents pollution . It is then placed in a fractionating column , where temperatures vary from 20 degrees celcius to 400 degrees celcius , various fractions are collected , such as bitumen , which is used to surface highways , paraffin wax , kerosene , petrol and many others .

The laboratory preparation of ethyl ethanoate

Ethyl ethanoate is an ester , an ester is a sweet smelling compound which is made using an acid and an organic alcohol in the presence of concentrated sulphuric acid and heat . In the laboratory it is prepared in a round bottomed flask , where ethanol and ethanoic acid are combined , together with concentrated sulphuric acid . The mixture is heated under reflux , that is , using a condenser so as to maximise the amount of ester obtained , the mixture is added to water , where the ester , being immiscible in the mixture and less dense than water , floats on top of the mixture and can be obtained by the use of the separating funnel .

The purification of copper

This is a simple process , where impure copper is made the anode and a thin strip of pure copper, the cathode , a solution of copper (II) sulphate with a small amount of concentrated sulphuric acid is the electrolyte . The anode breaks down by the passage of a current through it , forming Cu2+ ions which are discharged into the electrolyte . The Cu2+ ions are attracted to the cathode where they are deposited as solid copper , the impurities of the cathode then fall to the bottom of the electrolyte and pure copper can be obtained at the cathode . There is no change of colour throughout the process as the concentration of the electrolyte does not change .
The anode reaction is :
Cu ---------> Cu2* + 2e`
The electrons return to the circuit where they flow to the anode , at the anode they are used to form solid copper by combining with the Cu2+ ions .
The cathode reaction is :
Cu2* + 2e` ------> Cu
where solid copper is deposited


The manufacture of Sulphuric acid - The Contact Process

The first part of this process is the roasting of sulphur in the presence of oxygen ( air ) to form sulphur dioxide :
S + O2 ------> SO2
The second stage is the rate determining stage , here , sulphur trioxide is formed by compressing the sulphur dioxide and oxygen to 2 atmospheres , using a vanadium oxide or platinum catalyst and heating the mixture to 450 degrees celcius :
V2O5catalyst
2SO2 + O2 ------------> 2SO3
2atm , 450degrees
Vanadium oxide is preferred to platinum as it is cheaper and is contaminated less easily than platinum . It would seem that sulphur dioxide could be added directly to water to give sulphuric acid , however this reaction is extremely exothermic and thus dangerous to carry out , sulphuric acid is therefore added to the sulphur trioxide to form oleum which is very concentrated sulphuric acid :
SO3 + H2SO4 --------> H2S2O7
The oleum is now diluted with water to give sulphuric acid :
H2S2O7 + H20 ---------> 2H2SO4

The extraction of iron - the blast furnace

Iron is first extracted from iron oxide in the form of haematite by a reaction with carbon monoxide . The haematite is mixed with coke ( carbon ) and limestone to form the charge , this charge is then heated by hot air blown in to 1900 degrees celcius , here the coke reacts with air rich in oxygen , forming carbon dioxide :
C + O2 ------> CO2
The carbon dioxide now reacts with more coke where energy is absorbed and the temperature drops to 1100 degrees celcius , forming carbon monoxide :
CO2 + C ------> 2CO
This carbon monoxide now reacts with the haematite , forming iron and more carbon dioxide
3CO + Fe2O3 -------> 2Fe + 3CO2
The molten iron moves down the furnace and is now 700 degrees celcius , at temperatures above 850 degrees celcius , the limestone breaks down to calcium oxide and carbon dioxide:
850degrees
CaCO3 -------> CaO + CO2
This happens in the first 2 stages , one of the main impurities in the iron which must be got rid of is silica , SiO2 , this is done by the reaction of calcium oxide with silicon dioxide to form calcium silicate or slag , which floats on top of the iron and is removed separately .
CaO + SiO2 --------->CaSiO3
The iron is now obtained as it is separate from the iron , it has bout 4 percent impurities and is used to make wrought iron etc . The gases produced from the process are heated and used to heat up charge at the top of the furnace ( conservation ) , the slag is used as a fertiliser etc.



The moon
The moon , our little angel !
Does the average person know what the moon does , let me tell you what it does , according to Newton's third law of motion , if an object B applies a force on object A , object A applies an equal an opposite force on object B .
aFb = bFa
Simple huh , most ppl don't understand how far reaching that is though .
The earth , being much larger than the moon , applies a gravitational force on the moon , which keeps it in object round the earth , this force is a centripetal force without which there can be no motion . The average person should know that the moon applies a force on the earth too . This force is equal to the force applied by the earth to keep the moon in orbit round it , but being so much larger than the earth , the earth is affected visibly , but less drastically . The moon produces the effect of tides , but less known , is that the moon is needed to keep the earth in constant rotation on it's axis and translation round the sun . Without the moon , the earth would rotate between 0 and 90 degrees on it's axis , this means that within a space of about 6-8 hours ,the earth could have temperatures ranging from those of the Antarctic to those of the Sahara , from sub zero to 40 degrees centigrade and over . Without the moon , life as we know it would be completely different .
So when the President in Austin Powers 2 , the spy who shagged me , said to blow up the moon , " would we miss it ? " he questioned , of course we would , his advisers were smart enough to know that the consequences would be fatal .



Hypertension
Hypertension , by definition is high blood pressure . Persons more likely to be susceptible to it are persons who :
Are obese
Smoke
Stress
Have a bad structured diet
Whose relatives have the disorder

In persons who are obese , the heart has to work harder to pump blood through an increased volume , it therefore becomes enlarged and oversised as it must put out a pressure which it is not supposed to sustain . Eventually , the enlarged heart is not itself supplied with enough blood and can no longer function properly .With increased fat flowing through the blood system , the fat is deposited on the sides of the blood vessels like rust on the inside of an iron pipe , these are called plaques ( deposits of fatty material . ) Less blood flows through them as a whole , this results in the heart having to pump harder for blood to flow through the vessels . If the coronary artery , which supplies the heart with blood , is completely blocked , the heart cannot be supplied with oxygen and so stops contracting momentarily , this is called a heart attack which leaves the heart permanently damaged .

Nicotine in cigarettes , results in the constricting of blood vessels , so that they allow less blood to flow through them , the heart must therefore work harder to pump blood through them . Smoking also damages the lungs and so the heart has to work especially hard to pump blood through smaller , damaged passageways .

Persons who are in stressful situations may have their blood pressure at a high level , persons who experience very stressful jobs may have their blood pressure fail to return to normal after the job is over .

Persons who eat too much fatty material results in an increase in the formation of plaques and thus an increase in blood pressure . Also , a salt rich diet causes food to remain in the blood vessels resulting in a high blood pressure .

Persons whose family has a history of the disease are more susceptible to the disease .

Hypertension results in hardening of the arteries , especially the : brain , heart and kidneys , if the pressure in the body becomes too great , this can rupture a blood vessel in the brain , resulting in paralysis on one side of the body , loss of speech or even death . If the vessel to the kidneys becomes clogged , this results in less fluid being filtered , resulting in an increased amount of toxins in the body which can lead to disease , in extreme cases , the kidneys may fail completely , leading to further complications .


Digestion of food

The digestion of food - The digestion of food

Food contains many different substances , carbohydrates , fats , proteins as we all know are the main ones but there are many others . Here , I shall use a meal of steak and fries , the steak is the source of protein and some fat , and the fries are the carbohydrate .
Ingestion of food- Ingestion of food
You ingest food using the teeth , lips and tongue , the food is placed into the mouth and through the first process of mechanical digestion , the teeth break the food into smaller pieces so that there is a larger surface area for the action of enzymes on the food . The food is broken up into these smaller pieces , then saliva is secreted from the 3 pairs of salivary glands situated in the mouth , under the tongue . Saliva contains three substances : water , mucus and the enzyme amylase . Amylase serves to digest starch in the food in the mouth , however since the food stays in the mouth for a very short while , the enzyme does not usually have enough time to do this . Mucus is nothing new , it is found throughout the alimentary canal . There is no chemical digestion , that is the action of enzymes on the food being used yet , since only amylase is found here and very rarely can it begin digestion . After the food has been broken up enough mechanically , the tongue presses the bolus of food against the soft palate at the roof of the mouth , a reflex action then takes place where a flap of cartilage , called the epiglottis , covers the opening to the trachea , so that food does not go down the wrong passage . The bolus of food then travels down the oesophagus where by peristalisis , a process involving the contraction of the muscles of the alimentary canal to the bottom of the oesophagus before the stomach . There is a sphincter muscle located here , these muscles can close of the tube completely in certain places . The muscle gradually lets the food at intervals into the stomach .
Digestion of food - Digestion of food
In the stomach are gastric pits which are located in the stomach lining , these secrete hydrochloric acid which is necessary to produce an acid pH for the action of the stomach enzymes . The acid is also used to kill any bacteria in the food . There is only one enzyme present in the stomach , it is called pepsin and requires an acid environment . Pepsin is responsible for the breakdown of proteins into polypeptides , in the stomach of young mammals there is also an enzyme called rennin which is needed to clot the milk from the mothers so that it can be then broken down by pepsin . Mechanical digestion of the food also takes place here , where the stomach walls churn the food so that it can mix together with the gastric juice in the stomach . The food stays in the stomach for a varying period of time , this meal would stay for longer than an hour due to the high protein content . The stomach wall also contains mucous membranes to prevent the gastric juice eating away at the wall . After the time period , a sphincter muscle at the end of the stomach lets the chyme at intervals into the duodenum , the first part of the small intestine .
In the duodenum , two digestive juices are secreted , one is pancreatic juice which travels via the pancreatic duct , from a cream coloured gland situated just below the stomach . It contains three enzymes , lipase to digest fats (lipids) , amylase to digest starch and proteases to digest proteins . The other juice is bile , it is contains no enzymes and is a green coloured liquid formed as a bi product of the deamination of old red blood cells , the extra haemoglobin is used in the liver to make bile which is stored in the gall bladder , the bile travels to the duodenum via the bile duct . The bile contains sodium hydrogen carbonate which is used to neutralize the gastric juice so that the enzymes of the pancreatic juice can work properly . The proteins in the beef which were not digested into polypeptides in the stomach are broken down by the proteases to more polypeptides . The starch in the potato of the fries is now broken down to maltose by the amylase . Enzymes are biological catalysts , the substance at the beginning of the reaction is called the substrate and is broken down to a product at the end of the reaction , e.g. :
starch ----------> maltose
amylase
There are three parts of the small intestine , the duodenum , jejunum and ileum . The function of the bile is to digest fats , it breaks large drops of fat into smaller ones in a process known as emulsification . The fat in the steak is broken up like this , the food then travels through the jejunum where it is further broken down and then to the ileum where more enzymes are secreted. The enzymes secreted after the duodenum are , lipases , to break down the fats to fatty acids and glycerol , maltase to break down the maltose to glucose and fructose and trypsin to break down the polypeptides to amino acids . The definition of digestion is - the breakdown of large , complex , insoluble molecules to smaller , simple , soluble ones . The molecules are now small and simple and can now enter the blood , they can now pass through the walls of the alimentary canal. This is done via small (1mm) projections of the alimentary lining called villi which absorb fats , amino acids , glucose , vitamins , minerals etc..
Absorption of food - Absorption of food
There are lacteals in the villi who serve to absorb fats , and blood capillaries to pass the glucose etc.. to the liver to be processed , via the hepatic portal vein . If there is too much protein already in the blood , then the protein from the steak would be excess , it would be wasteful to excrete it as it is , so the excess protein is broken down , in a process known as deamination . The amino acid is broken down , the useful portion , containing energy , stored , as carbohydrate or fat and the part containing urea sent to the kidneys to be excreted . After the liver has processed the food, reabsorbing any excess glucose etc. the substances now enter the blood . The amino acids now enter the blood and are used for growth and repair , making enzymes , energy , making cell membranes , making antibodies and the glucose used for energy .
Only indigestible food is egested , since there was no plant material in the food , it is not egested and all substances are assimilated .